Commercial Grade Propane (Odorized)

24 Hour Emergency Assistance
PERS, Inc.
Accidents Spills or Leaks Only
1-800-633-8253

Section 1 - Identification

Section 2 - Ingredients

Section 3 - Physical Data

*Odorant Warning
Odorant is added to aid in detection of leaks. One common odorant is ethyl mercaptan, CAS No. 75-08-1. Odorant has a foul, skunk like odor. The odorant is effective in most instances, but not everyone can smell the odor. The ability of people to detect odors varies widely. Also, certain chemical reactions with material in the propane system can reduce the propane odor level. No odorant will be 100% effective in all circumstance. If odor level appears to be weak, notify propane supplier immediately.

Section 4 - Reactivity

Section 5 - Fire and Explosion Data

Evacuate area. Shut off source of gas, if possible. Notify Fire Department. Remain up-wind of vapors. Allow only trained, properly protected personnel in area. Shut off source of gas , if possible. Allow fire to burn itself out after gas flow is shut off. If gas flow cannot be shut off, do not extinguish fire. Allow fire to burn itself out using high volume water supply to cool heat-exposed pressure containers and nearby equipment. Approach a flame enveloped container from the side, never the head ends. Use extreme caution when applying water to a container which has been exposed to heat or flame for more than a short time. For uncontrollable fires and when flame is impinging on container, withdraw all personnel and evacuate vicinity immediately.

Firefighters should wear self-contained breathing apparatus in the positive pressure mode with full face piece. when there is a possibility of exposure to smoke, fumes or hazardous decomposition products. Uncontrolled vapors spread rapidly, are heavier than air and are extremely flammable.

Section 6 - Occupational Exposure Limits

Section 7 - Health Information

Exposure may produce rapid breathing, headache, dizziness, disturbance, muscular weakness, tremors, narcosis, unconsciousness, and death, depending on duration and concentration of exposure.

This gas is non-irritating, but direct contact with liquefied, pressurized gas or frost particles may produce severe and possible permanent eye damage from freeze burns.

This material is not expected to be absorbed through the skin. Non-irritating; but solid and liquid forms of this material and pressurized gas can cause freeze burns.

Solid and liquid forms of this material and the pressurized gas can cause freeze burns.

Personnel with pre-existing chronic respiratory diseases should avoid exposure to this material.

Section 8 - Emergency & First Aid Procedures

Immediately move personnel to fresh air. For respiratory distress, give air, oxygen, or administer CPR (cardiopulmonary resuscitation), if necessary. Obtain medical attention if breathing difficulties continue.

Vapors are not expected to present an eye irritation hazard. If contacted by liquid/solid, immediately flush the eye(s) gently with warm water for at least 15 minutes. Seek medical attention if pain or redness persists

Induce vomiting with warm water (qt.) only if patient is conscious. Immediately obtain medical attention.

Section 9 - Employee Protection

For excessive gas concentrations, use only NIOSH/MSHA self-contained breathing apparatus.

Use chemical-type goggles and face shield when handling liquefied gasses. Safety glasses and or a face shield are recommended when handling high pressure cylinders and piping system and whenever vapors are discharged.

Prevent potential skin contact with cold liquid/solid/vapors. Use insulated, impervious plastic or neoprene coated canvas gloves and protective gear (apron, face shield, etc.) to protect hands and other skin areas.

Section 10 - Environmental  Protection

Avoid uncontrolled releases of this material. Liquid releases will have possible effect on plant and animal life. Large liquid release will quickly vaporize to produce a large vapor cloud. Vapor cloud is both a fire and asphyxiation hazard.

Product is extremely flammable. Vapor is heavier than air and may collect at lower levels. If there is a leak but no fire, do not ignite the escaped gas. Eliminate all ignition sources. Water spray can be used to help dilute vapor concentration in air. If possible, remove leaking container to safe area.

Disposal of gas in accordance with applicable laws and regulations. Vent vapor in safe location and insure that gas dissipates below the lower flammable limit. Controlled burning is preferred.

Section 11 - Special  Protection

Store and use cylinders and tanks in a well ventilated area, away from heat and sources of ignition. No smoking near storage or use. Follow standard procedures for handling cylinders, tanks, loading/unloading. Fixed storage containers must be grounded and bonded during transfer of product.

Section 12- Regulatory Information

This product may contain over 1.0% propylene. This is subject to the reporting Section 313.

Immediate (acute) health hazard.

Sudden release of pressure hazard

All components of this product are listed on the TSCA inventory. The above information is based on the data of which we are aware and is believed to be correct as of the the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the data hereof may suggest notification of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shell make his own determination of the suitability of the material for his particular purpose.

The Safe Drinking Water and Toxic Enforcement Act 1986, commonly referred to as Proposition 65, requires the Governor to publish a list of chemicals "know to the State to cause cancer, birth defects, or reproductive harm." It also requires California businesses to warn the public quarterly of potential exposure to these chemicals which result from their operations. Liquefied Petroleum Gas (propane) , in its original state, contains radon and benzene, chemicals "know to the State of California to cause cancer." It also contains toluene a chemical " know to the State of California to cause reproductive harm." The benzene and toluene are destroyed when Propane is burned. Radon does not burn but is released with the combustion by-products. Radon and propane combustion by-products can generally be removed through appliance vents and other exhaust systems. When propane is processed in the some dehydrators, benzene and toluene can be released to the environment. A warning odorant is added to propane so that leaks of unburned gas can be quickly detected. If gas odor is detected, your supplier should be contacted promptly.